They meet after the time t from the departure
During this time, one goes through the distance
S1 = V1 * t
and the second goes through the distance
S2 = V2 * t
The sum of the two distances gives us total distance
S1 + S2 = S
Replace S1 and S2 in this last equation
V1 * + V2 * t = S
t (V1 + V2) = S where we take out the time they meet
t = S / (V1 + V2)
V1 = V2
t = 10 / 2V1 = 10/200 = 0.05 hours