The average atomic mass of Rb is 85.47 u.
The average atomic mass of X is the weighted average of the atomic masses of its isotopes.
We multiply the atomic mass of each isotope by a number representing its relative importance (i.e., its % abundance).
Thus,
0.7217 × 84.912 u = 61.282 u
0.2783 × 86.909 u = 24.187 u
TOTAL = 85.47 u