Liquid hexane CH3CH24CH3 reacts with gaseous oxygen gas O2 to produce gaseous carbon dioxide CO2 and gaseous water H2O . What is the theoretical yield of carbon dioxide formed from the reaction of 81.0g of hexane and 360.g of oxygen gas?

Respuesta :

The theoretical yield of carbon dioxide formed from the reaction of 81.0g of hexane and 360.g of oxygen gas is  312.63 grams

calculation

 step 1 :write the equation for reaction

2CH3(CH2)4CH3  +19 O2  →   12CO2  +14 H2O

step2:

   find moles of each reactant

mole= mass/molar mass

moles of CH3(CH2)4CH3 =  81 g / 86 g/mol = 0.942 moles

moles of O2=  360g/32  =11.25  moles

step 3:   find the moles of CO2

since O2 is the limiting reagent  and the mole ratio in equation above of O2 :CO2 is 19 :12 the moles of CO2

=  11.25 x12/19 =7.1053 moles

step  4: find the theoretical yield

= moles x  molar mass (44g/mol)

- 7.1053 moles x 44 g/mol= 312.63 grams

The theoretical yield of CO2 is 31.24 g of carbon dioxide.

The equation of the reaction is;

C6H14(l) + 19/2 O2(g) -----> 6CO2(g) + 7H2O(g)

Number of moles of hexane = 81.0g/86 g/mol = 0.94 moles

Number of moles of oxygen = 360.g/32 g/mol = 1.12 moles

To obtain the limiting reactant;

1 mole of liquid hexane reacts with 9.5 moles of oxygen

0.94 moles of liquid hexane reacts with 0.94 moles × 9.5 moles/ 1 mole

= 8.93 moles of oxygen

There is not enough oxygen hence it is the limiting reactant.

9.5 moles of oxygen yields 6 moles of carbon dioxide

1.12 moles of oxygen yields 1.12 moles × 6 moles/ 9.5 moles

= 0.71 moles of carbon dioxide

Mass of carbon dioxide = 0.71 moles of carbon dioxide × 44 g/mol

= 31.24 g of carbon dioxide

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