initially when balloon is in atmosphere then we have
[tex]PV = nRT[/tex]
initial temperature is T = 32 degree C
Initial pressure P = 1 atm
Initial volume V = 1.5 L
now we have number of moles as
[tex]n = \frac{1*1.5}{R*(32 + 273)}
similarly when it is submerged into the water
Temperature will be T = 21 degree C
Volume will be 0.5 L
now for same number of moles
[tex]PV = nRT[/tex]
[tex]P*0.5 = \frac{1*1.5}{R * 305}* R* (21+273)[/tex]
[tex]P = 2.89 atm[/tex]
so pressure at this depth will be 2.89 atm