If light is moving inside the glass, it will be reflected when the angle of incidence is above the critical angle of the material, which is given by
[tex]\theta_c = \arcsin ( \frac{n_a}{n_g} )[/tex]
where
[tex]n_a = 1.00[/tex] is the refractive index of air
[tex]n_g = 1.66[/tex] is the refractive index of this type of glass
If we plug the numbers into the equation, we find
[tex]\theta_c = \arcsin ( \frac{1.00}{1.66} ) = \arcsin (0.602) =37.0^{\circ}[/tex]
So, light will be reflected inside the glass when the angle is equal or greater than this value.