Respuesta :
Answer : Cu²⁺ ion can be most easily reduced.
Explanation :
Let us write the reduction reactions and the associated standard reduction potentials for the given ions.
1) [tex] Cu^{2+} + 2e^{-}\rightarrow Cu [/tex] [tex] E^{0}_{red}= 0.34 V [/tex]
2) [tex] Zn^{2+} + 2e^{-}\rightarrow Zn [/tex] [tex] E^{0}_{red}= -0.76 V [/tex]
3) [tex] Ni^{2+} + 2e^{-}\rightarrow Ni [/tex] [tex] E^{0}_{red}= -0.26 V [/tex]
4) [tex] Ca^{2+} + 2e^{-}\rightarrow Ca [/tex] [tex] E^{0}_{red}= -2.87 V [/tex]
If we look at the above standard reduction potential values, we see that standard reduction potential is highest for Cu²⁺ ion.
Higher the standard reduction potential, greater is the ability to undergo reduction.
Since Cu²⁺ ion has the highest standard reduction potential, it can be most easily reduced.